Persistent interactions between hydroxylated nanoballs and atactic poly(2-hydroxyethyl methacrylate)(PHEMA).

نویسندگان

  • Kadine Mohomed
  • Heba Abourahma
  • Michael J Zaworotko
  • Julie P Harmon
چکیده

The incorporation of self-assembled nanoparticles, a.k.a. hydroxylated nanoballs, into poly(2-hydroxyethyl methacrylate)(PHEMA) gives rise to a cross-linked network/hydrogel with enhanced interfacial interaction, whereas its inclusion in poly(methyl methacrylate)(PMMA) results in plasticization.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Poly (2-Hydroxyethyl Methacrylate) Macroporous Cryogel for Extracorporeal Medical Devices

Poly (2-hydroxyethyl methacrylate) PHEMA monolithic cryogels were synthesized by free radical polymerization at -12°C for 18 hours and produced spongy, elastic and macroporous gel matrix. Scanning Electron Microscopy (SEM) measured structural properties of PHEMA monolithic cryogel matrix to visualize pore morphology. Mechanical properties of PHEMA monolithic cryogel such as storage modulus, com...

متن کامل

Novel Synthesis of Cellulose-Based Diblock Copolymer of Poly(hydroxyethyl methacrylate) by Mechanochemical Reaction

The mechanical fracture of polymer produces polymeric free radical chain-ends, by which liner block copolymers have been synthesized. A diblock copolymer of microcrystalline cellulose (MCC) and poly 2-hydroxyethyl methacrylate (pHEMA) was produced by the mechanochemical polymerization under vacuum and room temperature. The fraction of pHEMA in MCC-block-pHEMA produced by the mechanochemical pol...

متن کامل

Patterned poly(2-hydroxyethyl methacrylate) brushes on silicon surfaces behave as "tentacles" to capture ferritin from aqueous solution.

We have used a very large scale integration process to generate well-defined patterns of polymerized 2-hydroxyethyl methacrylate (HEMA) on patterned Si(100) surfaces. An atom transfer radical polymerization initiator covalently bonded to the patterned surface was employed for the graft polymerization of HEMA to prepare the poly(2-hydroxyethyl methacrylate) (PHEMA) brushes. After immersing wafer...

متن کامل

Cellulose/poly (2-hydroxyethyl methacrylate) composites prepared via solution coagulation and subsequent bulk polymerization

Conditions are described for the preparation of eellulose/poly(2-hydroxyethyl methacrylate) (CELL/ PHEMA) composites from solutions of cellulose in dimethylacetamide-lithium chloride (DMAc LiCl) by coagulation with 2-hydroxyethyl methacrylate monomer and subsequent bulk polymerization of the coagulated films. The CELL/PHEMA composites obtained over a wide composition range were characterized ma...

متن کامل

Characterization of poly(2-Hydroxyethyl Methacrylate) Scaffolds for Tissue Engineering

Physical properties of scaffolds intended for myocardial tissue regeneration were studied. Mechanical properties and degradation rates were evaluated for degradable scaffolds composed of poly (2-hydroxyethyl methacrylate) (pHEMA) crosslinked with polycaprolactone (PCL). pHEMA copolymerized with tetraethylene glycol as a crosslinker served as a control. Fibroblast cells were used for cytotoxicit...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:
  • Chemical communications

دوره 26  شماره 

صفحات  -

تاریخ انتشار 2005